Vapour deposited lead free double perovskite for photovoltaic applications
Giulia Longo a, Henry J. Snaith a
a Oxford University, Department of Physics, United Kingdom
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV18)
Benidorm, Spain, 2018 May 28th - 31st
Organizers: Emilio Palomares and Rene Janssen
Oral, Giulia Longo, presentation 095
DOI: https://doi.org/10.29363/nanoge.hopv.2018.095
Publication date: 21st February 2018

In the last years organic-inorganic lead halide perovskites materials have attracted the interest of the research community thanks to their desired optoelectronic properties and due to the unprecedented scaling of their photovoltaic efficiency. However, the toxicity of the Pb atoms and the devices instability against moisture and temperature have hindered the commercialization of this technology. The substitution of the Pb2+ cation by a combination of a monovalent (M+) and a trivalent (M3+) cation to form double halide perovskites (A2M+M3+X6) has been considered an attractive alternative for the preparation of non-toxic and air stable devices. Despite the promising initial theoretical results on this class of materials, the preparation of high quality films of double perovskite is still challenging. The limited solubility of the inorganic precursors hampers the identification of a proper deposition route for the growth of thick and uniform layers suitable for photovoltaic applications. Vapour deposition techniques provide a valid alternative to overcome the limitation of the traditional wet chemistry methods, allowing the formation of a wide range of double perovskite compositions with a fine control over their thickness. In this talk we present the characterization of vapour deposited lead-free double perovskite and their implementation in photovoltaic devices.  

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