New Class of Green Low-Temperature Solution-Processed Metal Oxides for High Performance Organic Solar Cells
Wallace Choy a
a Department of Electrical and Electronic Engineering, The University of Hong Kong, Pok Fu Lam Road, Hong Kong SAR, China
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV18)
Benidorm, Spain, 2018 May 28th - 31st
Organizers: Emilio Palomares and Rene Janssen
Poster, Wallace Choy, 123
Publication date: 21st February 2018

While high-temperature evaporation and sputtering are commonly used for forming metal oxide semiconductors, we will discuss our room-temperature solution approaches for forming various metal oxides. To demonstrate their good electron and hole transport properties, we will use them for all solution-processed organic solar cells (OSCs) which can favor the efficient transport of carriers between the photoactive layer and electrode, and high transparency. Transition metal oxides are promising materials for carrier transport layers because of their good electrical properties, stability, and optical transmission. We propose and demonstrate several low-temperature solution-processed approaches for forming transparent and efficient metal oxide-based carrier transport layers including electron and hole transport layers [1]. With the incorporation of metal nanoparticles [2], the electrical and optical properties can be enhanced. The interesting features of the novel carrier extraction layers are low temperature, solution process and water free for high-performance optoelectronics such as OSCs with power conversion efficiency (PCE) of 12.1% [1-3]. In addition, we have developed some room-temperature processed Ag nano-network which can serve as transparent flexible electrodes [4]. With the knowledge of solution processed organic and inorganic materials, we also propose different approaches for highly stable and efficient perovskite SCs [5] with no hysteresis and most recent PCE of 20.5%.

[1] F.Jiang, W.C.H.Choy, et.al, Adv. Mat., 27, 2930, 2015; F.Xie, W.C.H.Choy, et.al., Adv. Mat., 25, 2051, 2013; S.Lu, W.C.H.Choy, et al, Adv. Energy Mat., 5, 1500631, 2015; X.C. Li, W.C.H.Choy, et.al. Adv. Function. Mat., 24, 7348, 2014.

[2] F.X.Xie, W.C.H.Choy, et al, Energy Environ. Sci., 6, 3372, 2013; D.Zhang, W.C.H.Choy, et.al. ACS Nano, 7, 1740, 2013;X.Ren, W.C.H.Choy, et.al, Small, 12, 5200,2016

[3] J.Cheng, W.C.H.Choy*, et.al. Adv Funct. Mater., 2018, DOI:10.1002/adfm.201706403

[4] H.Lu, W.C.H.Choy, et. al. Adv Funct. Mat., 25, 4211, 2015.

[5] F.X. Xie, W.C.H.Choy, et.al., ACS Nano, 9, 639, 2015; H.Zhang, W.C.H.Choy, et al. ACS Nano, 10, 1503, 2016; H.Zhu, W.C.H.Choy, et. al., ACS Nano, 10, 6808, 2016; J.Mao, W.C.H.Choy, et. al., Adv. Funct. Mat., DOI:10.1002/adfm.201606525.; H.Zhang, W.C.H.Choy,et.al, Adv.Mat. DOI:10.1002/adma.201604695.

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