Singlet Fission to Enhance Photovoltaic Efficiency
Neil Greenham a
a Cavendish Laboratory, University of Cambridge - UK, JJ Thomson Avenue, 9, Cambridge, United Kingdom
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV18)
Benidorm, Spain, 2018 May 28th - 31st
Organizers: Emilio Palomares and Rene Janssen
Invited Speaker, Neil Greenham, presentation 143
DOI: https://doi.org/10.29363/nanoge.hopv.2018.143
Publication date: 21st February 2018

The efficiency of photovoltaic devices could be improved beyond the Shockley-Queisser limit if it were possible to convert higher-energy photons in the solar spectrum into two bandgap-energy photons. The process of singlet exciton fission in organic semiconductors is a promising route to achieve this, but the challenge is to achieve photon emission from both of the triplet excitons generated following photon absorption. Triplet energy transfer into emissive lead sulfide nanoparticles has been demonstrated, with the potential to achieve a “photon multiplier film” than could be applied to the front surface of a silicon solar cell. I will present recent progress in this area, aiming to achieve highly luminescent nanoparticles whilst still allowing triplet excitons to tunnel easily onto the particles from a surrounding organic singlet fission material.  I will also present new results studying luminescence under high magnetic fields to understand the interactions between triplet excitons generated by singlet fission.

© FUNDACIO DE LA COMUNITAT VALENCIANA SCITO
We use our own and third party cookies for analysing and measuring usage of our website to improve our services. If you continue browsing, we consider accepting its use. You can check our Cookies Policy in which you will also find how to configure your web browser for the use of cookies. More info