Material Design for Fullerene-free Polymer Solar Cells with Over 14% Efficiency
Jianhui Hou a
a Beijing National Research Center for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China, China
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV18)
Benidorm, Spain, 2018 May 28th - 31st
Organizers: Emilio Palomares and Rene Janssen
Invited Speaker, Jianhui Hou, presentation 194
DOI: https://doi.org/10.29363/nanoge.hopv.2018.194
Publication date: 21st February 2018

Solution-processed bulk heterojunction (BHJ) polymer solar cells (PSCs) have exhibited great potentials for making large area and flexible solar panels through low-cost solution coating techniques. Typically, a BHJ active layer in a PSC is composed of a conjugated polymer as electron donor and an organic compound as electron acceptor. In recent years, the applications of non-fullerene-based small molecular acceptors materials have afforded great opportunities to achieve higher power conversion efficiency (PCE) in PSCs. In comparison with the PSCs based on fullerene-based acceptors like PCBM, photovoltaic performance of the fullerene-free PSCs are even more sensitive to the intrinsic properties of the polymer donors and non-fullerene acceptors in their active layers. In the past year, our group focused on the study of material design for fullerene-free PSCs and achieved a series of high performance PSCs. Based on these studies, we suggested a few feasible methods for molecular design of the donors and the acceptors and also tried to correlate the molecular energy levels, aggregation morphologies and other intrinsic properties of the active layer materials with their photovoltaic behaviors in device. Furthermore, we used the polymer donors and small molecular acceptors with the optimized chemical structures to construct a single-junction and double-junction tandem PSC with PCEs over 14%.

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