Carbon-sandwiched perovskite solar cells as the solutions of cost and stability
Namyoung Ahn a, Il Jeon b, Jungjin Yoon a, Esko Kauppinen c, Yutaka Matsuo b, Shigeo Maruyama b, Mansoo Choi b
a Global Frontier Center for Multiscale Energy Systems
b Seoul National University, 104-1 - 509, Seoul National University, Inter-University Semiconductor Research Center, 1 Gwanak-ro, Gwanak-gu, Seoul, 151, Korea, Republic of
c University of Tokyo, Japan, Japan
d Department of Applied Physics, Aalto University, P.O.Box 15100, Espoo, FI-00076 AALTO, Finland
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV18)
Benidorm, Spain, 2018 May 28th - 31st
Organizers: Emilio Palomares and Rene Janssen
Poster, Namyoung Ahn, 311
Publication date: 21st February 2018

As an alternative of conventional solar cells, perovskite solar cells are currently promising due to their high performance. The technology, however, shares the critical problem of low-stability which prevent their commercialization. In this respect, a new approach to address stability issues is still required and important. Moreover, it brings us a dramatic potential if the approach not only improve the stability, but also go the fabrication cost down. In this work, we propose carbon allotropes-sandwiched structure, in which fullerene bottom layer as an electron transporting layer resolves low stability induced by widely-used TiO2 layer and carbon nanotube top electrode layer functioning as both hole transporting and electrode layers offers high stability and low-cost merits. Carbon allotropes-sandwiched devices fabricated using different hole-transporting materials infiltrated into carbon nanotube networks were compared to find out the best solution to stability and cost. We measured time evolution of power conversion efficiency under constant one sun illumination to examine their lifetime. As a consequence, polymeric hole-transporting layers show much longer lifetime when infiltrated into carbon nanotube networks because of their compact nature and stronger interaction with the carbon network, which is evidenced by computation calculation and water vapor transmission rate results. Finally, the encapsulated carbon allotropes-sandwiched perovskite solar cells including polymeric hole-transporting layer showed high stability against both air and light, maintaining up to 85% of the initial efficiency after 2200 hours under actual operation conditions. Cost analysis also shows that our carbon-sandwiched approach brings the fabrication cost down to less than 5.5% compared with conventional devices employing Au electrode. Our study suggests a promising cell structure for highly stable and low-cost perovskite photovoltaic technologies.

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