Copper Thiocyanate as an Inorganic HTM for Perovskite Solar Cells
Daniel Williams a
a SPECIFIC-IKC, Swansea University Bay Campus, Crymlyn Burrows, Sw, Swansea, United Kingdom
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV16)
Swansea, United Kingdom, 2016 June 29th - July 1st
Organizers: James Durrant, Henry Snaith and David Worsley
Poster, Daniel Williams, 303
Publication date: 28th March 2016

Traditionally perovskite solar cells have been fabricated with an organic hole transport material (HTM) such as spiro-OMeTAD due to the high efficiencies that are achievable. However, organic HTM are usually quite expensive because of the complex synthetic procedures or the need for high purity. As a result there is a need for a low cost and efficient inorganic HTM. Copper Thiocyanate (CuSCN) has been proposed as a possible inorganic replacement HTM. It is cost competitive, has excellent transparency, high chemical stability and hole mobility, has been shown to be capable of high efficiencies and can be solution processed so that it is compatible with existing perovskite solar cell processing, more importantly, at low temperatures. Here we investigate the effects of varying the concentration of the HTM precursor on the UV-vis absorption and attempt to fabricate high efficiency lead halide perovskite-based solar cells. Initial results show that varying the concentration has little to no effect on the absorption in the visible light range but does have a big effect on the UV range. 



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