Device-oriented perovskite crystallization
Pablo P. Boix a
a Instituto de Tecnología Química, Universitat Politècnica de València - Consejo Superior de Investigaciones Científicas (UPV-CSIC), Avd. de los Naranjos s/n, Valencia 46022, Spain
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV24)
València, Spain, 2024 May 12th - 15th
Organizer: Bruno Ehrler
Invited Speaker Session, Pablo P. Boix, presentation 067
Publication date: 6th February 2024

Metal halide perovskites have emerged as promising alternatives to traditional semiconductors, yet their practical implementation faces several challenges that limit their impact in society. In particularly, material stability and performance areas have been key aspects that affect perovskite photovoltaics as well as various semiconductor-based applications. Overcoming these obstacles necessitates precise tuning of the material, and strategies such as crystallization control or additive engineering become crucial.

Here, we introduce comprehensive approach to perovskite formation control that enable the optimization of the systems for specific applications. As a result, we design techniques such as an in-situ highly efficient nanocrystals fabrication approach through humidity-induced methods [1], additive adjustment for efficient and stable Pb-free perovskite solar cells, and a laser-based passivation of macrocrystal surfaces [2]. Through a thorough investigation into the physical properties of these monocrystals, we explore their impact on diverse applications, such as photovoltaic devices and memristors [3]. Leveraging the robustness of monocrystalline systems, we develop an impedance spectroscopy model to analyze the phase dispersion resulting from ionic modulation, providing valuable electrical insights applicable to polycrystalline thin-film devices. Our research contributes to advancing high-performance metal halide perovskite devices by elucidating crucial factors influencing their performance and proposing potential solutions to enhance their functionality.

The work was partially funded by MCIN/ AEI through project TED2021-131600B-C32, by Generalitat Valenciana via Pla Gent-T (grant CIDEXG/2022/34) and by the research project no. PID2020-119628RB-C31 funded by MCIN/ AEI /10.13039/501100011033.

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