Perovskite Silicon Tandem Solar Cells for Resource Efficient Photovoltaics
Jan Christoph Goldschmidt a, Patricia S. C. Schulze b, Lukas Wagner b, Özde Ş. Kabaklı b, Jonas Bartsch b, Alexander J. Bett b, Martin Bivour b, Raphael Efinger b, Oussama Er-Raji b, Thibaud Hatt b, Minasadat Heydarian b, Maryamsadat Heydarian b, Christoph Luderer b, Christoph Messmer b c, Martin Schubert b, Oliver Schultz-Wittmann b, Leonard Tutsch b, Stefan W. Glunz b c, Martin Hermle b
a Physics of Solar Energy Conversion, Department of Physics, Philipps-University Marburg, Germany
b Fraunhofer Institute for Solar Energy Systems ISE, Heidenhofstrasse 2, 79110 Freiburg, Germany, Freiburg, Germany
c Laboratory for Photovoltaic Energy Conversion, Albert-Ludwigs-Universität Freiburg, DE, Germany
Materials for Sustainable Development Conference (MATSUS)
Proceedings of nanoGe Spring Meeting 2022 (NSM22)
#PMSC22. Perovskite-based multijunction solar cells
Online, Spain, 2022 March 7th - 11th
Organizers: Stefaan De Wolf and Steve Albrecht
Invited Speaker, Jan Christoph Goldschmidt, presentation 079
DOI: https://doi.org/10.29363/nanoge.nsm.2022.079
Publication date: 7th February 2022

Resource limitations are becoming increasingly important for Terawatt-scale photovoltaics.  Reducing the CO2-emissions from processing, substantially reducing the silver demand and ramping up flat-glass production capacity must become key priorities. Furthermore, high-efficiencies obtainable by perovskite-silicon tandem solar cells are one strong leverage to reduce overall resource demand. Here, we report on record high currents for planar perovskite silicon tandem devices by more transparent TCOs and adapted layer thicknesses.  Using a TCO stack design, soft damage free processing could be combined with low parasitic absorption. We outline how further layer and interface optimization, as well as the application of textured bottom solar cells can lead to over 30% efficiency. We discuss, how usage of critical materials and costs can be reduced. First by the implementation of TOPCon-based bottom solar cells, with a PERC-like rear structure and a silicon tunnel junction front. Second, by the first-time successful demonstration of copper plating on perovskite solar cells.

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