Composition-Tuning in Colloidal Lead Halide Perovskite Nanocrystals by cation-Exchange
Lakshminarayana Polavarapu a
a CINBIO, Universidade de Vigo Materials Chemistry and Physics Group, Department of Physical Chemistry Campus Universitario Lagoas, Marcosende, 36310 Vigo, Spain
Materials for Sustainable Development Conference (MATSUS)
Proceedings of nanoGe Spring Meeting 2022 (NSM22)
#PerNC22. Colloidal Metal Halide Perovskite Nanocrystals: From Synthesis to Applications
Online, Spain, 2022 March 7th - 11th
Organizers: Maksym Kovalenko, Maryna Bodnarchuk and Osman Bakr
Invited Speaker, Lakshminarayana Polavarapu, presentation 216
DOI: https://doi.org/10.29363/nanoge.nsm.2022.216
Publication date: 7th February 2022

Over the last few years, halide perovskite nanocrystals (NCs) have received great attention in many fields ranging from chemistry to physics and engineering owing to their extremely interesting properties such as defect tolerance, high photoluminescence quantum yield (PLQY), tunable optical bandgap not only by their dimensions but also by composition, enhanced stability compared to thin-film perovskites, and ease of synthesis. In general, ion exchange reactions offer access to NCs with precise chemical compositions that are inaccessible by direct synthetic routes. While anion (halide)-exchange in halide perovskite NCs has been greatly exploited to tune their optical properties, cation exchange has been less explored. This talk will be focused on post-synthetic cation-composition tuning in lead halide perovskite NCs for fine-tuning their optical properties.

L. P. acknowledges the support from the Spanish Ministerio de Ciencia e Innovación through Ramón y Cajal grant (RYC2018-026103-I) and the Spanish State Research Agency (Grant No. PID2020-117371RA-I00), the grant from the Xunta de Galicia (ED431F2021/05).

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