Processing Organic Solar Cells from Green Solvents
Thuc-Quyen Nguyen a
a Center for Polymers and Organic Solids and Department of Chemistry and Biochemistry University of California, Santa Barbara
Materials for Sustainable Development Conference (MATSUS)
Proceedings of nanoGe Spring Meeting 2022 (NSM22)
#StEffOPV22. Novel concepts for highly stable and efficient organic solar cells
Online, Spain, 2022 March 7th - 11th
Organizers: Vida Engmann, Morten Madsen and Jeff Kettle
Invited Speaker, Thuc-Quyen Nguyen, presentation 279
DOI: https://doi.org/10.29363/nanoge.nsm.2022.279
Publication date: 7th February 2022

Organic solar cells (OSCs) using non-fullerene acceptors (NFAs) have garnered a lot of attention during the last years and showed dramatic increases in the power conversion efficiency (PCE). PCEs higher than 19% for single-junction systems were achieved, but these high-performance organic photovoltaic cells are often processed with halogenated solvents. To accelerate the mass fabrication of OSCs, green solvent processing is crucial to reduce the harmful effect of halogenated solvents to human health and our environment. In this talk, I will discuss the design, synthesis, and performance of organic semiconductors processed from green solvents such as xylene and 2-methyl tetrahydrofuran (2-MeTHF). 2-MeTHF can be obtained from furfural, which is derived from agricultural by-products. It fits within the class of solvents sought from renewable resources and the concept of capitalizing on waste to generate useful chemicals.  Moreover, the toxicity of 2-MeTHF is lower than that of commonly used halogenated and aromatic solvents, such as chlorobenzene and chloroform.  A combination of characterization methods were employed to gain insight into the film morphology and solar cell performance.

 

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