Optical characterization & analysis routines of photogenerated carriers and mobile ions in perovskite
Weijian Chen a, Xiaoming Wen b, Baohua Jia b, Xiaojing Hao a
a University of New South Wales, Australian Centre for Advanced Photovoltaics, School of Photovoltaic and Renewable Engineering, Sydney 2052, Sydney, Australia
b Swinburne University of Technology, Centre for Translational Atomaterials, Hawthorn, Hawthorn VIC 3122, Australia, Hawthorn, Australia
Proceedings of International Conference on Advanced Light Absorbing Materials for Next Generation Photovoltaics (ABSOGEN)
Online, Spain, 2020 November 17th - 18th
Organizers: Hongxia Wang, Xiaojing Hao and Lydia Wong
Oral, Weijian Chen, presentation 006
Publication date: 6th November 2020

Organic-inorganic hybrid perovskite solar cells are very promising photovoltaics with a fastly increasing efficiency of over 25%. But the instability of the performance is currently one of the significant technical barriers to their commercialization. Mobile ions migration/accumulation is reported to be the physical mechanism for performance instability, I-V hysteresis, and performance changes during light soaking. An extensive comprehension of how illumination/light-soaking influence perovskites are of fundamental significance to improve the stability of its optoelectronic applications. In this report, a light soaking study on several kinds of perovskites monocrystalline and polycrystalline film will be discussed via temporal-resolved and detection-wavelength selective micro-imaging spectroscopic techniques.[1-5] These works clarify different roles of mobile ion and charge carriers and demonstrate the advantages of the imaging spectroscopy in studying the carrier dynamics of perovskite-based materials under light soaking.

This work is supported by the Australian Government through the Australian Renewable Energy Agency. Responsibility for the views, information, or advice expressed herein is not accepted by the Australian Government.

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