Preparation and Optimization of Materials for Efficient Perovskite Solar Cells
Songyuan Dai a b, Xu Pan b, Linhua Hu b, Jianxi Yao a
a Beijing Key Laboratory of Novel Thin Film Solar Cells,Renewable Energy School, North China Electric Power University, Beijing, 102206, P. R. China
b Key Laboratory of Novel Thin Film Solar Cells, Institute of Applied Technology, Chinese Academy of Sciences, Hefei, Hefei, China
Asia-Pacific International Conference on Perovskite, Organic Photovoltaics and Optoelectronics
Proceedings of International Conference Asia-Pacific Hybrid and Organic Photovoltaics 2018 (AP-HOPV18)
Kitakyūshū-shi, Japan, 2018 January 28th - 30th
Organizers: Shuzi Hayase, Juan Bisquert and Hiroshi Segawa
Invited Speaker, Songyuan Dai, presentation 054
DOI: https://doi.org/10.29363/nanoge.ap-hopv.2018.054
Publication date: 27th October 2017

A novel mesoporous ETL based on La doped BaSnO3 (LBSO) is investigated here. The LBSO nanoparticles are synthesized under relatively mild conditions and proved to be a suitable material for mesoporous ETL. After optimization, solar cells using mesoporous LBSO show the best power conversion efficiency of 15.1%.

A uniform, pinhole-free and incomplete pore filling in porous TiO2 film of PbI2-free perovskite layer was prepared by the sandwich structure MAI-PbI2-MAI precursor film. Compare to the conventional two-step method, the devices fabricated from the sandwich structure MAI-PbI2-MAI precursor films shown a dramatic improvement for all the performance parameters, and a promising efficiency of 17.8% was achieved.

A new class of hole-transporting materials (HTM) containing tetraphenylmethane (TPM) core have been developed. After thermal, charge carrier mobility, and contact angle tests, it was found that TPA-TPM (TPA: arylamine derivates side group) showed higher glass-transition temperature and larger water-contact angle than spiro-OMeTAD with comparable hole mobility.By adopting low pressure vapor assisted process (LP-VASP), we systematic studied the effect of the type of A cation, the type of X halide, and the structure on the photovoltaic properties. In LP-VASP, the evolution of crystal structure and mechanism of carriers transport showed many different results compared with that of the PSC prepared by solvent approaches. We achieved PCE of 17.40% in planar PSCs with mixed halide sources. There are some studies going on based on LP-VASP, such as the introduction the pseudohalogen into the structure of ABX3.

References

X. Zhang, J. Ye, L. Zhu, H. Zheng, X. Liu, X. Pan and S. Dai, ACS Appl. Mater. Interfaces, 2016, 8, 35440-35446.

L. Zhu, Z. Shao, J. Ye, X. Zhang, X. Pan and S. Dai, Chem. Commun., 2016, 52, 970.

L. Zhu, J. Ye, X. Zhang, H. Zheng, G. Liu, X. Pan and S. Dai, J. Mater. Chem. A, 2017.

T. Du, N. Wang, H. Chen, H. Lin, H. He, ACS Appl. Mater. Interfaces 2015, 7 (5), 3382-3388.

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