Exploring the Solid-State Optical Properties of Indium Arsenide Core and Core–Shell Colloidal Quantum Dots
Eleftheria Charalambous a b, Nefeli Polycarou b, Paris Papagiorgis a, Andreas Manoli a, Sotirios Christodoulou b, Grigorios Itskos a
a Experimental Condensed Matter Physics Laboratory Department of Physics, University of Cyprus, Nicosia 1678, Cyprus
b Inorganic Nanocrystals Laboratory, Department of Chemistry, University of Cyprus, Nicosia 1678, Cyprus
Proceedings of Emerging Light Emitting Materials 2025 (EMLEM25)
La Canea, Greece, 2025 October 8th - 10th
Organizers: Maksym Kovalenko and Grigorios Itskos
Poster, Eleftheria Charalambous, 076
Publication date: 17th July 2025

Indium arsenide (InAs) quantum dots (QDs) emerged recently as promising greener alternatives to lead- and mercury-based chalcogenide infrared QDs. Advances in synthesis have made it possible to produce stable InAs QDs with improved luminescence properties and applications in light emitting and light harvesting devices. Despite the progress, many aspects of the fundamental electronic properties of such QDs, especially in the form of thin films are still elusive.

In this work, we employ variable-temperature, steady-state and transient photoluminescence (PL) measurements to study the photophysics of drop-casted films of InAs core and InAs/ZnS, InAs/ZnSe core/shell QDs. Shell growth improves the passivation of deep surface traps, leading to up to an order-of-magnitude increase in PL quantum yield and up to a threefold extension of the PL lifetime. On the other hand, shallow surface traps appear to mediate thermally activated exciton trapping and de-trapping processes, giving rise to a non-monotonic temperature dependence of both the PL intensity and the PL lifetime. Modelling of the results suggests that the average depth of such shallow traps increases upon shell formation, possibly due to emergence of interfacial core–shell trap states. The work provides some initial insight into the excitonic and defect-level structure of colloidal InAs QD-based solids.

© FUNDACIO DE LA COMUNITAT VALENCIANA SCITO
We use our own and third party cookies for analysing and measuring usage of our website to improve our services. If you continue browsing, we consider accepting its use. You can check our Cookies Policy in which you will also find how to configure your web browser for the use of cookies. More info