The Electrochemical Stability of P-I-N Perovskite Solar Cells Assembled Using Different Electron-transport Layer Materials
Regina Vavilina a b, Olga Yamilova b c, Pavel Troshin b c
a D. Mendeleev University of Chemical Technology of Russia, Russian Federation
b Skoltech - Skolkovo Institute of Science and Technology, Moscow, Bolshoy Boulevard 30, Moskva, Russian Federation
c The Institute for Problems of Chemical Physics of the Russian Academy of Sciences RAS, Russia, Semenov Prospect 1, Russian Federation
Proceedings of Online School on Hybrid, Organic and Perovskite Photovoltaics (HOPE-PV)
Online, Spain, 2020 November 3rd - 13th
Organizers: Sergey M. Aldoshin, Jovana Milic, Keith Stevenson and Pavel Troshin
Poster, Regina Vavilina, 056
Publication date: 23rd October 2020
ePoster: 

In recent years, solar cells based on complex lead halides demonstrate an extraordinary growth in power conversion efficiency (PCE), which now exceeds 25% for the best laboratory samples. However, the practical application of perovskite solar cells is still hampered due to their low operational stability. In addition to the widely studied effects of photochemical and thermal degradation, a special attention should also be paid to electrochemical stability of absorber materials and the solar cells. In this work, electrochemical stability of perovskite solar cells assembled with various electron-transport layer (ETL) materials was systematically compared. Devices with oxide-based ETLs such as ZnO and SnO 2 were exposed to the constant electric field in inert atmosphere in the dark and at a room temperature to exclude the influence of other stress factors such as light or heat. The evolution of the solar cell efficiency under the applied bias was analyzed and the obtained results revealed that electrochemical stability of perovskite solar cells is highly dependent on the used ETL material. It was also shown that short biasing of PSC with ZnO ETL can enhance significantly their efficiency.
Thus, the obtained results emphasize the importance of multi-parameter optimization of the device structure and, most importantly, the composition of the electron-transport layer, to achieve the long-term operational stability
of the perovskite solar cells.

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