Novel Ruthenium dyes as Sensitizers for Dye-Sensitized Solar Cells
Yue Hu a, Neil Robertson a
a University of Edinburgh, School of Chemistry, West Mains Road., Edinburgh, 0, United Kingdom
International Conference on Hybrid and Organic Photovoltaics
Proceedings of 6th International Conference on Hybrid and Organic Photovoltaics (HOPV14)
Ecublens, Switzerland, 2014 May 11th - 14th
Organizers: Michael Graetzel and Mohammad Nazeeruddin
Poster, Yue Hu, 047
Publication date: 1st March 2014

Dye-sensitised solar cells (DSSCs) are devices which convert solar energy into electrical energy via photoexcitation of the dye molecules. Many aspects of DSSCs have been investigated to improve their efficiency,but one of the most significant factors is the sensitising dye.

 

Research into new sensitising dyes is increasingly focused on designing complexes that can absorb visible to near-IR light with high molar extinction coefficients. Also, the dye size needs to be considered for a better dye coverage of the electrode surface.

 

Considering these, my research is currently focused on making new dyes containing an azo ligand as the chromophore group to allow a combinationof the best aspect of organic dye (high absorption coefficient) with those of Ru dyes(good stability, low aggregation, better red absorption and long excited-state lifetime). These dyes were prepared using a protection/deprotection strategy that allows for convenient purification.  The optical and photophysical properties were characterised through electrochemical, spectroscopic and computational techniques. DSSCs devices were fabricated and tested.


The novel Ru complex containing azo ligand shows better absorption than N3.
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