Proceedings of 6th International Conference on Hybrid and Organic Photovoltaics (HOPV14)
Publication date: 1st March 2014
Whether used as the top cell in a multi-junction stack or to drive electrochemical reactions, solar cells with high open circuit voltages (VOC) are an important tool in the efforts for sunlight energy harvesting. Achieving this requires a combination of a suitable energy band structure together with good charge collection kinetics. Solution-processed organic-inorganic lead halide perovskite absorbers, with their high open circuit voltage to band-gap ratio, are particularly suited for this purpose.
Here methylammonium lead bromide and its mixed halide form, both with an optical band-gap of 2.3 eV were used as absorbers in a mesoporous p-i-n device configuration. Through judicious selection of the organic hole conductor with suitable band alignment and band-gap to minimize losses, a solar cell showing Voc above 1.5 V and short circuit currents of ca. 4 mA/cm2 was demonstrated. Analysis of the loss mechanisms and the proposed route for further improvement of the cell performance is discussed.