The Effect of First-step PbI2 Concentration on CH3NH3PbI3 Perovskite Hybrid Solar Cells Fabricated by a Sequential Deposition Method
Hong Lin a, Ye Zhang a, Zhibo Yao a, Jianbao Li a b
a Key Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan University, Haikou, 570228, China
International Conference on Hybrid and Organic Photovoltaics
Proceedings of 6th International Conference on Hybrid and Organic Photovoltaics (HOPV14)
Ecublens, Switzerland, 2014 May 11th - 14th
Organizers: Michael Graetzel and Mohammad Nazeeruddin
Oral, Hong Lin, presentation 099
Publication date: 1st March 2014

Methylammonium lead perovskite hybrid solar cells, which have been the research forefront, have realized highly efficient and stable photovoltaic devices. For solution-processable perovskite-based solar cells, a two-step sequential deposition method allows facile and complete transition from PbI2 to CH3NH3PbI3 perovskite. In this sense, in the initial step, the PbI2 loading has thus become a critical factor in determining the device performance. In this work, we changed the PbI2 precursor concentration and corresponding devices were assembled. It was found that for the first-step deposition of PbI2, larger concentration led to stronger light-absorption. However, a concentration of over 1 M would presumably give rise to particle conglomeration and formation of grain boundaries, causing the photovoltaic performance to degrade. With help of myriad characterizations using XRD, SEM, UV-Vis spectra, and IPCE, we identified an optimal condition to fabricate such hybrid solar cells with a power conversion efficiency of 7.4% under AM1.5G illumination in the air. Investigation regarding steady-state photoluminescent quenching and carrier diffusion lifetime measurements from a time-resolved fluorescence spectrometer was also conducted with results discussed.


UV-Vis absorption spectra of CH3NH3PbI3 perovskite with different PbI2 precursor concentration. Inset: photo images of fabricated PbI2 (up) and CH3NH3PbI3 perovskite (bottom) with different concentrations (from left to right: 0.4 M, 0.6M, 0.8M, and 1.0 M)
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