Proceedings of 6th International Conference on Hybrid and Organic Photovoltaics (HOPV14)
Publication date: 1st March 2014
Ageing of organic solar cells is one of the last impediments left to overcome to reach industrial production. PEDOT:PSS layer in an inverted architecture, prepared from acid solutions, has been identified as a life time limitation factor. Therefore, many efforts have been made on replacing this polymer by oxide materials, which are expected to be more stable due to their inorganic nature. Organic solar cells incorporating transition metal oxides as hole transporting layer have shown good performances. Moreover, a special attention has been given to develop wet deposition methods compatible with industrial fabrication. Nanoparticle-based solution deposition methods do not require high temperature annealing compared to Sol-Gel methods which usually leave organic residue deteriorating the electrical properties. This work presents the synthesis of tungsten oxide nanoparticles and their wet process deposition in organic solar cells. Microwave assisted heating has led to a fast synthesis of WOx nanoparticles with a narrow size distribution. High stability in solution has been obtained, allowing the formation of homogeneous thin films. OPV devices have been realized and their performances have been assessed by J-V curves measurements. With P3HT:PCBM as an active layer, power conversion efficiency of 3,2% and 2,5% have been obtained in standard and inverted structures and aging experiments have also been carried out. The effect of annealing conditions of the whole stack in inverted structure has been studied. These performances have been compared to reference cells using PEDOT:PSS. Consequences of aging on electronic properties and on inorganic/organic interface are in progress.