Proceedings of 6th International Conference on Hybrid and Organic Photovoltaics (HOPV14)
Publication date: 1st March 2014
Colloidal quantum dot (CQD) solar cells with solution-producible absorber layers have made rapid progress in the last few years. In particular, the so-called depleted heterojunction concept, consisting of a wide band gap n-type semiconductor and a p-type CQD film as absorber, appears promising. Here, we study the potential of CuInS2 nanocrystals (NCs) as a relevant alternative to the toxic Pb or Cd compounds for usage in depleted heterojunction solar cells. Two different layer stacks, based on a bilayer heterojunction between CIS and ZnO NCs, were investigated by means of high resolution electron microscopy and optical modeling. We applied variable-angle spectroscopic ellipsometry to derive the optical constants of the involved layers. These data served as input parameters into optical simulations in order to estimate light absorption in the individual layers of the device stack with the transfer matrix formalism. Furthermore we investigated the distribution of the electric field throughout the device in dependence of the ZnO optical spacer thickness. Here, we present the simulated data in comparison with experimental results.