Side Chain Engineering to Improve the Efficiency and Stability of Solution-Processed Bulk Heterojunction Small Molecule Solar Cells
Jie Min a, Chaohua Cui b, Yongfang Li c, Christoph Brabec d
a Institute of Materials for Electronics and Energy Technology (I-MEET), Friedrich-Alexander-University Erlangen-Nuremberg, Martensstrasse 7, Erlangen, 91058, Germany
b Chemical Engineering and Materials Science, Soochow University, Suzhou 215123
c Chemical Engineering and Materials Science, Soochow University, Suzhou 215123
d Institute of Materials for Electronics and Energy Technology (I-MEET), Friedrich-Alexander-University Erlangen-Nuremberg, Martensstrasse 7, Erlangen, 91058, Germany
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV16)
Swansea, United Kingdom, 2016 June 29th - July 1st
Organizers: James Durrant, Henry Snaith and David Worsley
Oral, Jie Min, presentation 012
Publication date: 28th March 2016

Thin-film organic solar cells (OSCs) have received significant attention due to the advantages of light-weight, flexibility, low cost, and facile fabrication of roll-to-roll processing.[1] However, there are three key issues that have to be considered carefully for future practical applications: high power conversion efficiency (PCE), good processability and long-term stability.[2] In this work, we designed and synthesized three small molecules, namely BDTT- TR (meta-alkthienyl), BDTT-O-TR (meta-alkoxy-thienyl) and BDTT-S-TR (meta-alkylthio-thienyl), to systematically elucidate the effects of alkyl side chains on the relevant device properties. Although these three molecules show the similar molecular structure, thermal property and optical band gap, the introduction of meta-alkylthio-thienyl-substituted BDT as the central unit in the molecular backbone substantially results in the higher absorption coefficient, lower highest occupied molecular orbital (HOMO) level and more efficient and balanced charge transport property in BDTT-S-TR system. Combining with the investigations of morphological characteristics and carrier recombination mechanisms in BHJ blends, BDTT-S-TR device has been strongly demonstrated that it possesses a higher power conversion efficiency (PCE) of 9.20% as compared to the other two systems (7.44% for BDTT-TR and 6.50% for BDTT-O-TR). In addition, the influence of active layer thicknesses on device performance has been investigated for further assessing these molecules for possible large-scale production. Finally, the thermal stability of blend morphology and light-induced degradation in devices are also investigated. Our aim is to provide a comprehensive summary insight into the structure-property interrelationship, meanwhile underline the effects of defined molecular structures that represent the observed trade-offs in device efficiency and blend processability as well as the relevant stability. 



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