The Influence of Side Chain Manipulation of Conjugated Polymers on the Stability of Polymer Solar Cells
Eva Bundgaard a, Ilona Heckler a, Jurgen Kesters b, Wouter Maes b
a Technical University of Denmark, Department of Energy Conversion and Storage, Frederiksborgvej, 399, Roskilde, Denmark
b Hasselt University, Institute for Materials Research (IMO-IMOMEC), Wetenschapspark, 1, Diepenbeek, Belgium
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV16)
Swansea, United Kingdom, 2016 June 29th - July 1st
Organizers: James Durrant, Henry Snaith and David Worsley
Oral, Ilona Heckler, presentation 029
Publication date: 28th March 2016

The field of conjugated polymers for polymer solar cells (PSCs) has been studied intensively over the past two decades. The primary focus is still to reach high power conversion efficiencies using highly advanced polymers in small-area PSCs. Nowadays, the focus also includes the processing of PSCs on a large scale and their long-term stability. The stability of PSCs has increased from minutes to years, which has been done both by using stable monomer units [J. Mater. Chem., 2011, 21, 3222] and focusing on the side chains. Vanderzande et al. [Macromolecules, 2011, 44, 8470]described an increase in the thermal stability of a bulk heterojunction active layer blend based on a poly(p-phenylene vinylene) derivative by replacing the dimethyloctyloxy side chains with 2-phenylethoxy groups, leading to a noticeable increase in the glass transition temperature of the resulting polymer material. Further studies on poly(3-alkylthiophene) materials showed the influence of partly exchanging the side chains with other functional groups to result in more stable PSCs [Org. Electron., 2014, 15, 549].Polymers found to be suitable in a roll-coating process [Adv. Energy Mater., 2015, 5, 1402186] were manipulated by changing the side chains to influence the long-term stability. One example of such a polymer is a low band gap polymer based on benzo[1,2-b:4,5-b’]dithiophene donor and benzo[c][1,2,5]thiadiazole acceptor parts. To ensure a high solubility of the polymers in organic solvents, only 5 and 10% of the side chains were exchanged. In this presentation, the influence of such manipulation of the solubilizing side chains on the solar cell performance and their lifetime will be presented.



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