The High-Efficiency Dye Sensitized Solar Cell Using Cobalt Electrolyte in Dim-Light Application
Peter Chen a, Sean Sung-Yen Juang a, Yu-Sheng Chen a, Yu-Chun Wu b, Yu-Ling Guo b
a Department of Photonics,National Cheng Kung University, No.1, University Road, Tainan, 701, Taiwan, Republic of China
b Department of Resources Engineering,National Cheng Kung University, No.1, University Road, Tainan, 701, Taiwan, Republic of China
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV16)
Swansea, United Kingdom, 2016 June 29th - July 1st
Organizers: James Durrant, Henry Snaith and David Worsley
Oral, Sean Sung-Yen Juang, presentation 068
Publication date: 28th March 2016

As the age of IOT and portable devices applications is coming, energy harvesting under indoor or dim-light environment is becoming critical. Dye-sensitized solar cell (DSC), a technology that performs extremely well under these conditions has found unique advantages for its utilization in such scenario. In this report, we investigate the use of [Co(bpy)3]3+/2+ (bpy=2,2’-bipyridine) redox mediators in MPN (3-methoxypropionitrile) solvent under low light (200 lux) condition. The effect of redox concentration, electrolyte additives and pore size of titania are scrutinized. Under the optimized condition, the power density output under 200 lux achieved 12 µW/cm2, which outperformed the best device using the conventional uses I-/I3- redox mediators illuminated with the same light intensity. Co electrolyte is well known for its advantages in minimizing the energy redundancy for charge separation. On the other hand, the issue of diffusion limit will not be crucial at low-light condition. Results of I-V characteristic, IPCE, and electrochemical impedance spectroscopy  (EIS) are applied to analyze the working mechanism. We believe the information revealed in our study is useful for developing further indoor applications in the future.



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