Efficiency Improvement in Inverted Organic Photovoltaics with Nanocrystalline Layer
Hyeok Kim a, Jun Young Kim  b, Hyeonho Lee  c, Changhee Lee
a KITECH/UST, 13-13 Hayang-ro, Gyeongsan, 38430, Korea, Republic of
b OLED Advanced Technology Team, LG Display, 245, LG-ro, Wollong-myeon, Paju-si, Gyeonggi-do, 413-779, Korea, Republic of
c Department of Electrical and Computer Engineering, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul, 151742, Korea, Republic of
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV16)
Swansea, United Kingdom, 2016 June 29th - July 1st
Organizers: James Durrant, Henry Snaith and David Worsley
Oral, Hyeok Kim, presentation 113
Publication date: 28th March 2016

Organic photovoltaics (OPVs) are of great interest due to their low-cost, flexible and eco-friendly properties for future energy source. In this talk, we demonstrate that nanocrystalline zinc oxide thin film doped with various metals as an interlayer can remarkably enhance the efficiency of inverted polymer photovoltaics based on the bulk heterojunction with the mixture of [6,6]-phenyl C71-butyric acid methyl ester (PC70BM) and diverse donors, such as poly[4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b]dithiophene-2,6-diyl][3-fluoro-2-[(2- ethylhexyl)carbonyl]thieno[3,4-b]-thiophenediyl (PTB7) and poly[[9-(1-octylnonyl)-9H-carbazole-2,7-diyl]-2,5-thiophenediyl-2,1,3-benzothiadiazole-4,7-diyl-2,5-thiophenediyl] (PCDTBT). Recently, it was reported that metal doping of ZnO thin film such as Li, Al, or Ga is an effective way to modify the grain size and orientation of ZnO crystallites. It can highly affect the structural, optical and electrical properties. Here, we adopted various metal dopants to inverted organic solar cells. As a result, the doped ZnO film with a number of dopants, such as Al, Ga, In, Li and Cd, was prepared by sol-gel spin coating method and a certain doping concentration is obtained in each case. Al doped ZnO (AZO) film with ca. 6 at. % Al concentration, for the case, was intercalated between the ITO electrode and the active layer (PTB7:PC70BM), the power conversion efficiency increases from 6.1 % to 8.4 %.



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