Extraction and Characterization of Black Carrots as Natural Sensitizers for Dye-Sensitized Solar Cells.
Jessica Barichello a, Antonio Bartolotta b, Giuseppe Calogero b
a Department of Environmental Sciences, Informatics and Statistics ,Ca' Foscari University of Venice, Via Torino 155, 30107 Mestre (VE), Italy
b CNR-IPCF, viale F. Stagno D'Alcontres 37, MESSINA I- 98158, Italy
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV16)
Swansea, United Kingdom, 2016 June 29th - July 1st
Organizers: James Durrant, Henry Snaith and David Worsley
Poster, Giuseppe Calogero, 195
Publication date: 28th March 2016

In this contribution, the most significant advances made in the search for low cost natural sensitizers based on anthocyanins are reported through meaningful examples and case studies. We extract with different techniques raw anthocyanins from black carrots. By using selected natural dyes, overall conversion efficiencies above 1% under simulated sunlight have been achieved, which is comparable to that of natural photosynthesis. From the black carrots, we obtained a dark-blue extract employing two new methods: one based on acetone and another based on acid water solutions. We studied the effect of the electrolyte composition on the sensitizer performances and the effect of the thickness of TiO2 layers. Black carrots� solar conversion efficiency was deeply improved by a progressive optimization of the photoanode TiO2 multilayer and of the electrolyte compositions overcoming the best performance reported in literature so far. It�s worth to emphasize that, although presently natural vegetable based DSCs are still below the efficiency requirements for practical applications, our results indicate that these pigments are promising candidates to be potentially exploited, in the future, for production of non-toxic, cheap and fully biodegradable tandem dye-sensitized solar cells and as co-sensitizers since their absorption spectra is complementary to that of others dyes



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