A Simple Method to Evaluate the Effectiveness of Encapsulation Materials for Perovskite Solar Cells
Tim Wilderspin a, Francesca DeRossi a, Trystan Watson a
a SPECIFIC, Swansea University, Baglan Bay Innovation and Knowledge Centre, Baglan, SA12 7AX, United Kingdom
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV16)
Swansea, United Kingdom, 2016 June 29th - July 1st
Organizers: James Durrant, Henry Snaith and David Worsley
Poster, Tim Wilderspin, 231
Publication date: 28th March 2016

Solution processable perovskite solar cells are generating great interest in the research community due to their simple production and impressive efficiencies, now demonstrated at over 20%. However, significant issues with stability are causing serious concerns despite these high efficiencies. Successful entry to market will continue to be limited while these issues remain. 

Perovskite films can degrade due to a number of factors which include water and oxygen exposure or cumulative effects of several causes. Previous research has shown that  a common breakdown mechanism for perovskite solar cells is the degradation of the MAPbI3  Perovskite into lead iodide PbI2 and MAI, this typically occurs when the material is exposed to humid conditions. It is understood that effective encapsulation against this is vital for long device lifetime. This work introduces the use of time lapse photography and RGB colour analysis to continuously monitor degradation of perovskite solar cells through the time-dependant formation of lead iodide. The method enables a wide range of encapsulation techniques and materials to be assessed simultaneously. This simple method is supported by XRD analysis and UV-Vis Spectroscopy.



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