Study of Three Novel Bismuth Based Organic-Inorganic Compounds as Lead-Free Solar Absorbers
Tianyue Li a, Neil Robertson a
a University of Edinburgh, School of Chemistry, West Mains Road., Edinburgh, 0, United Kingdom
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV16)
Swansea, United Kingdom, 2016 June 29th - July 1st
Organizers: James Durrant, Henry Snaith and David Worsley
Poster, Tianyue Li, 251
Publication date: 28th March 2016

During the last few years, rapid emergence of organic-inorganic halide perovskites solar cells along with the ever-increasing efficiency has led to a new era of solar energy research. Lead based perovskite solar cells are central to the efficiency rise, however the toxicity of lead and the adverse effects to the environment must be of concern. In this work, three different bismuth-iodide based inorganic-organic hybrid compounds have been studied for their potential to be alternatives to lead-based perovskites in the solar cell. Specifically, [CH3(C5H5N)]4Bi2I10 with one-dimensional chain structure, (C5H6N)4Bi2I10 with one-dimensional chain structure, and (C5H7N2)3[Bi2I9]2 dimer have been prepared and studied. Their structures have been investigated with single crystal X-ray diffraction; electrochemical and optical properties have been characterized to assess their potential as light absorbers in solar cells. Furthermore, the band structures and orbital energies have been calculated, and spin-coating carried out to prepare thin films for potential low-cost manufacturing. Applications of these materials in solar cells will be discussed and could lead to promising future materials for lead-free third generation photovoltaics.



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