Layered Organic Tin Halide Perovskite: Interfacial Charge Carrier Dynamics and Device Applications
Luis Lanzetta a, Sozos Michael a, Chloe Wong a, Saif A. Haque a
a Department of Chemistry and Centre for Plastic Electronics, Imperial College London, South Kensington Campus, London, United Kingdom
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV18)
Benidorm, Spain, 2018 May 28th - 31st
Organizers: Emilio Palomares and Rene Janssen
Poster, Luis Lanzetta, 069
Publication date: 21st February 2018

In spite of the exciting future prospects shown by organic lead halide perovskite solar cells (PSCs), challenges such as premature material degradation and Pb toxicity must be addressed for this technology to become commercially available. In this direction, Sn-based perovskites have emerged as the main alternative to tackle Pb content in PSCs, showing promising charge carrier mobility and nearly ideal bandgaps. Nevertheless, their lack of stability in ambient conditions (e.g. easy oxidation of Sn2+ to Sn4+) causes unwanted p-type doping in the material, leading to excessive non-radiative recombination and device shorting. Recently, layered tin-based perovskites have been introduced as a way to slow material degradation and achieve high device efficiency and reproducibility.1–3

This presentation will focus on our latest research on layered hybrid tin halide perovskite. Specifically, the optolectronic properties of 2D (PEA)2SnI4 vs 3D CH3NH3SnI3 will be discussed, as well as the incorporation of the low-dimensional material in light-emitting diodes.4 Furthermore, the interfacial charge transfer and recombination reactions in layered perovskites will be described via Transient Absorption Spectroscopy and Time-Resolved Photoluminescence studies, highlighting the role of multiphase systems. Last but not least, the use of layered tin perovskites in solar cells and the role of the organic spacer will be elucidated.

 

1          ACS Energy Lett., 2017, 2, 982–990.

2         J. Am. Chem. Soc., 2017, 139, 6693–6699.

3         Adv. Energy Mater., 2017, 1702019.

4         ACS Energy Lett., 2017, 2, 1662–1668.

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