Efficient semitransparent perovskite minimodule with highly transparent and conductive multilayer electrode
Soo-Jin Moon a, Adriana Paracchino a, Gabriel Christmann a, Ludovic Lauber a, Julien Brossard a, Arnaud Walter a, Brett A. Kamino a, Christophe Ballif a b, Sylvain Nicolay a
a CSEM, PV-Center, Jaquet-Droz 1, 2002 Neuchâtel, Switzerland
b École Polytechnique Fédérale de Lausanne (EPFL), Institute of Microengineering (IMT), Photovoltaics and Thin-Film Electronics Laboratory (PV-Lab), CH, Rue de la Maladière, 71, Neuchâtel, Switzerland
International Conference on Hybrid and Organic Photovoltaics
Proceedings of 13th Conference on Hybrid and Organic Photovoltaics (HOPV21)
Online, Spain, 2021 May 24th - 28th
Organizers: Marina Freitag, Feng Gao and Sam Stranks
Oral, Soo-Jin Moon, presentation 042
Publication date: 11th May 2021

Energy consumption of building sector has been increasing rapidly due to population growth, improved levels of wealth and lifestyle changes. Moreover, the buildings and buildings construction sectors combined are responsible for 40 % of total carbon dioxide emissions. In order to reduce CO2 emission, energy generation from fossil fuel has to be replaced with renewable energy. Therefore, demands of the Building Integration Photovoltaics (BIPV), which makes possible the power generation from roofs, windows or facades have increased. In order to integrate PV into windows or facades of buildings, semitransparency or transparency of the solar cells is essential. The organometallic halide perovskite (PK) solar cells can be semitransparent by tuning their thickness and with transparent contact. Moreover, PK solar cells have achieved a very high efficiency (>25 % certified efficiency) and could be processed with low costs. Hence, PK solar cells satisfy almost all the requirement for BIPV applications.

In this talk we present our work on the semitransparent PK modules fully laser patterned. We optimized thickness and transmittance of sputtered ITO/Ag/ITO multilayers for transparent contact. The ITO/Ag/ITO multilayers have high transmittance of 75 % in visible region from 400nm to 800nm and very low sheet resistance of 4-5Ω/□. Combination of thin NiO layer and semiconducting polymer significantly reduced shunts on large area substrates and patterning by femtosecond laser increased geometric fill factor (GFF) over 95% compared to nanosecond laser. Finally, semitransparent perovskite modules achieved a power conversion efficiency of 15.6 % with an aperture area of 13.68 cm2. Moreover, there is almost no efficiency difference between semitransparent modules and 1 cm2 cells.

 

 

The authors gratefully acknowledge the financial support from the Korea Electric Power Coporation (South Korea) and EU Horizon 2020 grant H2020-LCE-2015-16-53296 CHEOPS.

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