Safe Lead (Pb) Management of Perovskite Solar Cells
Rene Daniel Mendez Lopez a b, Barry Breen b, David Cahen a c
a Bar-Ilan University, Israel, Ramat Gan, 52900, Israel, Israel
b 3GSolar Photovoltaics Ltd., 3 Hamarpeh Street, POB 45216, Jerusalem, 91451, Israel
c Weizmann Institute of Science, Herzl St. 234, Rehovot, Israel
International Conference on Hybrid and Organic Photovoltaics
Proceedings of 13th Conference on Hybrid and Organic Photovoltaics (HOPV21)
Online, Spain, 2021 May 24th - 28th
Organizers: Marina Freitag, Feng Gao and Sam Stranks
Invited Speaker Session, Rene Daniel Mendez Lopez, presentation 057
Publication date: 11th May 2021

Halide perovskites have been widely explored in photovoltaics research due to their outstanding properties as light absorbing materials. The most efficient devices use Pb-based halide perovskite. PbI2 and PbBr2, together possibly with oxide/hydroxides, are the most likely decomposition products if cells are broken and the perovskite is exposed to the ambient. These decomposition products show some solubility in water, so rain can lead to Pb reaching the groundwater. Such a scenario carries environmental and public health risk. We show here how to mitigate and even eliminate this scenario by efficient sequestering of lead. We show a scheme of ligands for sequestration as part of an encapsulation, using commercially viable materials and methods, reaching till now 85% lead retention within insoluble products (that can be removed from a disaster zone, i.e., reduce the problem to that of commercial CdTe-based cells), using commercially viable materials and methods.

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