Investigating Triarylamine Polymer Derivatives as Hole Transport Layers in FACsPbI3 Perovskite Solar Cells
Zhongyao Jiang a, Chieh-Ting Lin b, Tian Du b, Thomas J Macdonald b, Yi-Chun Chin b, Weidong Xu b, Bowen Ding b, Martin J Heeney b, Martyn A McLachlan a
a Department of Materials and Centre for Plastic Electronics, Imperial College London, London, W12 0BZ, United Kingdom
b Imperial College London, Exhibition Road, United Kingdom
International Conference on Hybrid and Organic Photovoltaics
Proceedings of 13th Conference on Hybrid and Organic Photovoltaics (HOPV21)
Online, Spain, 2021 May 24th - 28th
Organizers: Marina Freitag, Feng Gao and Sam Stranks
Oral, Zhongyao Jiang, presentation 093
Publication date: 11th May 2021

Metal halide perovskite solar cells (PSCs) are one of the most promising photovoltaic technologies to date, with their reported power conversion efficiencies (PCEs) increasing from 3.8 % in 2009 to over 25 % today. In this study, we aim to improve the photovoltaic parameters of PSCs through interface engineering. Specifically, we focus on enhancing device open circuit voltage (Voc), which is one of the most limiting parameters associated with losses in PCE.

Numerous studies have shown that Voc losses can be attributed to non-radiative recombination within bulk perovskite films and/or at the interface between charge transport layers. Here, strategies to improve Voc by suppressing non-radiative losses through interface engineering will be discussed. Specifically, we investigate two triarylamine polymer derivatives- PTAA and PF8TAA -as hole transport layers (HTLs) in FACsPbI3 PSCs. Using a suite of optical, structural and electrical characterisation techniques we study modifications in microstructure, absorption and stability of PSCs prepared using these HTLs. Our results focus on the impact of the energy of the highest occupied molecular orbital (HOMO) level of the HTL and the impact this has on device performance and lifetime.

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