Enhanced Blue Photosensitizer for Dye-Sensitized Solar Cells employing a Copper-based Redox Mediator
Natalie Flores Diaz a b
a Newcastle University
b Ecole Polytechnique Federale de Lausanne, Station 16, Lausanne, Switzerland
International Conference on Hybrid and Organic Photovoltaics
Proceedings of 13th Conference on Hybrid and Organic Photovoltaics (HOPV21)
Online, Spain, 2021 May 24th - 28th
Organizers: Marina Freitag, Feng Gao and Sam Stranks
Oral, Natalie Flores Diaz, presentation 098
Publication date: 11th May 2021

Dye-sensitized solar cells (DSCs) based on copper(II/I) redox mediators have readily attained high open-circuit voltages (Voc) of over 1 V, but relatively low short-circuit photocurrent densities. To achieve high power conversion efficiency (PCE), the development of extended spectral-response photosensitizers compatible with the copper-based electrolytes while attaining a high Voc is crucial. Herein, a blue photosensitizer coded R7 was reported, which was purposely designed for highly efficient DSCs with copper-based electrolytes. R7 features a strong electron-donating segment of 9,19-dihydrobenzo[1',10']phenanthro[3',4':4,5]thieno[3,2-b]benzo[1,10]phenanthro[3,4-d]thiophene conjugated with an bulky auxiliary donor N-(2',4'-bis(hexyloxy)-[1,1'-biphenyl]-4-yl)-2',4'-bis(hexyloxy)-N-methyl-[1,1'-biphenyl]-4-amine and the electron acceptor 4-(7-ethynylbenzo[c][1,2,5]thiadiazol-4-yl)benzoic acid. The blue dye R7 with bulkier auxiliary donor moiety in the DSC largely outperforms the reference dye R6 with a smaller bis(4-(hexyloxy)phenyl)amine donor unit.[1] Transient absorption spectroscopy and electrochemical impedance spectroscopy measurements show that the R7 based DSC has a higher charge separation yield, a higher charge collection efficiency, and a slower interfacial charge recombination than the R6 based counterpart. A co-sensitized system of R7 and Y123 for the DSC presents an outstanding PCE of 12.7% and maintains 90% of its initial value after 1,000 h of continuous full sunlight soaking at 45 oC. The work sheds light on future designs of organic photosensitizers for highly efficient copper-based DSCs.

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