The Role of Terminal Group Position in Triphenylamine Based Self-Assembled Hole-Selective Monolayers in Perovskite Solar Cells
Ece Aktas a b, Rajesh Pudi a, Nga Phung c, Robert Wenisch d, Marion A. Flatken c, Iver Lauermann d, Antonio Abate c e, Emilio Palomares a f
a Institute of Chemical Research of Catalonia (ICIQ-BIST), Avinguda dels Països Catalans, 16, Tarragona, Spain
b Departament de Química-Física i Inorgànica. URV. E-43007. Spain., Campus Sescelades, Edifici N4, 2ona planta C/ Marcel.lí Domingo, 1, Tarragona, Spain
c Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Kekuléstr. 5, Berlin D-12489, Germany.
d PVcomB/Helmholtz-Zentrum Berlin für Materialen und Energie, Schwarzschildstraße, 3, Berlin, Germany
e Department of Chemical, Materials and Production Engineering, University of Naples Federico II, Piazzale Vincenzo Tecchio, Napoli, Italy
f ICREA. Passeig LLuís Companys 23. E-08010. Spain.
International Conference on Hybrid and Organic Photovoltaics
Proceedings of 13th Conference on Hybrid and Organic Photovoltaics (HOPV21)
Online, Spain, 2021 May 24th - 28th
Organizers: Marina Freitag, Feng Gao and Sam Stranks
Poster, Ece Aktas, 163
Publication date: 11th May 2021
ePoster: 

Recent application of self-assembled monolayers as a charge selective layer in perovskite solar cells has gained tremendous attention. Highly efficient and stable devices have been released with stand-alone SAMs binding on ITO substrates, however, further understanding about the effect of the structure of SAM on PSCs is required. Herein, three triphenylamine-based self-assembled hole selective small molecules have been synthesized by placing different positioned dimethoxy phenyl substituents. They have been effectively employed in p-i-n PSCs and the highest power conversion efficiency is reached 19.8% which is comparable with commercially available materials. The para-&ortho- positioned substituents provide larger perovskite grain size that ensures to obtain higher power conversion efficiency.

 

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