White light emission from lead-free mixed-cation doped Cs2SnCl6 nanocrystals
Samrat Das Adhikari a, Carlos Echeverría-Arrondo a, Rafael S. Sánchez a, Vladimir S. Chirvony b, Juan P. Martínez-Pastor b, Saïd Agouram c d, Vicente Muñoz-Sanjosé c d, Iván Mora-Seró a d
a Institute of Advanced Materials (INAM), Universitat Jaume I, Castelló de la Plana, Castelló 12006, Spain
b Instituto de Ciencia de Materiales (ICMUV), Universidad de Valencia, Carrer del Catedrátic José Beltrán Martinez, 2, Paterna, Spain
c Department of Applied Physics and Electromagnetism, University of Valencia (UV), Spain, Valencia, Spain
d Unitat Mixta d’Investigació UV-UJI, Materials for Renewable Energy (MAER), Spain
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV22)
València, Spain, 2022 May 19th - 25th
Organizers: Pablo Docampo, Eva Unger and Elizabeth Gibson
Poster, Samrat Das Adhikari, 085
Publication date: 20th April 2022

We have designed a synthesis procedure to obtain Cs2SnCl6 nanocrystals (NCs) doped with metal ion(s) to emit visible light. Cs2SnCl6 NCs doped with Bi3+, Te4+ and Sb3+ ions emitted blue, yellow and red light, respectively. In addition, NCs simultaneously doped with Bi3+ and Te4+ ions were synthesized in a single run. Combination of both dopant ions together gives rise to the white emission. The photoluminescence quantum yields of the blue, yellow and white emissions are up to 26.5, 28, and 16.6%, respectively under excitation at 350, 390, and 370 nm. Pure white-light emission with CIE chromaticity coordinates of (0.32, 0.33) and (0.32, 0.32) at 340 and 370 nm excitation wavelength, respectively, was obtained. The as-prepared NCs were found to demonstrate a long-time stability, resistance to humidity, and an ability to be well-dispersed in polar solvents without property degradation due to their hydrophilicity, which could be of significant interest for wide application purposes.

DROP-IT (European Union's Horizon 2020 Research and Innovation Program)

Ministry of Science and Innovation of Spain under Project STABLE

Ministry of Economy and Competitiveness of Spain (MINECO-FEDER)

Generalitat Valenciana via Prometeo Grant Q-Devices

SCIC (Universitat Jaume I)

SCSIE (University of Valencia)

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