Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV24)
Publication date: 6th February 2024
Nowadays, polyurethane-based materials are massively exploited in a plethora of applications, from adhesives to foams, from building insulations to athletic tracks. Recently, the specifical use of aliphatic thermosetting polyurethanes (aPUs) has enormously increased in the industrial context for their versatile synthesis and tunable physicochemical properties. In the context of photovoltaics, and more specifically, the emerging field of Perovskite Solar Cells (PSCs), we proposed the use of thermosetting polyurethanes as low-cost but effective encapsulants on rigid devices. [1]
The advantage of thermosetting PUs over other polymeric encapsulants lies in their tunable flexibility. Indeed, a properly designed combination of precursors leads to a PU that could be coupled with PET in flexible PSCs, allowing PU-protected devices to outperform the non-encapsulated cells in both conventional and high-humidity (RH > 70%) environments. Another possibility with thermosetting PU is their application as both encapsulant and interlayer in tandem devices; more in detail, we exploited a specifically designed formulation (i.e., having a refractive index comparable to the one of glass and a transmittance higher than 90%) to glue together a NIR-Dye Sensitized Solar Cell and a UV-absorbing PSC. The final tandem device reached a total efficiency close to 10% with an Average Visible Transmittance (AVT) as high as 35%, leading to a Light Utilization Efficiency close to 3.5%. All the proposed formulations have been engineered to improve their sustainability by replacing fossil fuel precursors with bio-based or waste-derived ones [2], thus leading to high-performing but sustainable encapsulants and interlayers for emerging photovoltaics.
This project has received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No 826013. This research acknowledges support from the Project CH4.0 under the MUR program “Dipartimenti di Eccellenza 2023-2027” (CUP D13C22003520001). S.G. ackowledges support from project NODES which has received fundings from the MUR-M4C2 1.5 of PNRR funded by the European Union - NextGenerationEU (Grant agreement no. ECS00000036).
This study is a result of the research project “nuovi Concetti, mAteriali e tecnologie per l’iNtegrazione del fotoVoltAico negli edifici in uno scenario di generazione diffuSa” (CANVAS), funded by the Italian Ministry of the Environment and the Energy Security, through the Research Fund for the Italian Electrical System (type-A call, published on G.U.R.I. n. 192 on 18-08-2022).
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International Conference on Hybrid and Organic Photovoltaics
International Conference on Hybrid and Organic Photovoltaics (HOPV) is celebrated yearly in May. The main topics are the development, function and modeling of materials and devices for hybrid and organic solar cells. The field is now dominated by perovskite solar cells but also other hybrid technologies, as organic solar cells, quantum dot solar cells, and dye-sensitized solar cells and their integration into devices for photoelectrochemical solar fuel production.
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The main topics of the Asia-Pacific International Conference on Perovskite, Organic Photovoltaics and Optoelectronics (IPEROP) are discussed every year in Asia-Pacific for gathering the recent advances in the fields of material preparation, modeling and fabrication of perovskite and hybrid and organic materials. Photovoltaic devices are analyzed from fundamental physics and materials properties to a broad set of applications. The conference also covers the developments of perovskite optoelectronics, including light-emitting diodes, lasers, optical devices, nanophotonics, nonlinear optical properties, colloidal nanostructures, photophysics and light-matter coupling.
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