Exploration of High-Efficiency, Low Bandgap Polymer Solar Cells towards Tandem OPV-OPV configurations.
Valentina Carrarini a, Jacopo H. Rahmani a, Andrea Reale a
a CHOSE (Centre for Hybrid and Organic Solar Energy), Department of Electronic Engineering, University of Rome “Tor Vergata”, 00133 Rome, Italy
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV25)
Roma, Italy, 2025 May 12th - 14th
Organizers: Filippo De Angelis, Francesca Brunetti and Claudia Barolo
Poster, Valentina Carrarini, 279
Publication date: 17th February 2025

Recent advances in Non-Fullerene Acceptors (NFAs) have significantly enhanced the
performance of organic photovoltaics (OPVs), addressing limitations in energy level tuning,
light absorption, and charge mobility. The development of ITIC-type (2015) and Y6-type
(2019) NFAs has enabled power conversion efficiencies (PCE) exceeding 15%. [1][2][3]
Current certified records show PCEs of 20.5% for single-junction and more than 14% for
organic-organic tandem OPV devices. [4][5] Despite this rapid progress, challenges remain
in further improving efficiency, stability, and scalability. [2] Research at the NanoMicrofab
Laboratory, University of Rome Tor Vergata, targets these challenges through the design,
fabrication, and characterization of OPVs using low band-gap donor and NFA materials. Both
inverted and direct single-junction architectures have been optimized. Ongoing work
focuses on tandem devices development to achieve high-performance, scalable, and
versatile-in-application systems in the field of energy harvesting applications and non-
infrastructure-based communication technologies.

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