Publication date: 11th March 2026
At the beginning of the 21st century, carbon neutral and sustainable energy sources need to be considered instead of exhaustible fossil fuels to meet the growing demand and combat global warming. Within this very challenging race for alternative energy sources, metal halide perovskite solar cells (PSCs) have undergone unprecedented progress with efficiencies reaching now 26.95% and even over 30% in tandem configuration1 and sparked great excitement in the photovoltaics community due to their flexibility and ability to be synthesized at low cost.
However, since hybrid halide perovskites have a highly ionic character, they can decompose under external stresses such as moisture, solvents and heating cycles.2,3,4 Reducing environmental stresses imposed by moisture or oxygen for example, in order to improve the long-term stability of perovskite solar cells, is critical to the deployment of this technology.
In this communication, we will discuss the preliminary development of new electron
transport layers (ETLs) and their use in inverted perovskite solar cells (PSCs). The present study concentrated on two distinct methodologies, utilizing small molecules in one case and polymers in the other. The utilization of these materials has the potential to create a more compact layer, thereby protecting the perovskite layer from oxygen and water. This is a significant challenge in the field of PSCs and requires further study.5 Crosslinking has been demonstrated to enhance mechanical strength, a critical factor in ensuring durability. Furthermore, cross-linkable ETLs have the potential to act as an insulating layer against harmful environments and for lead sequestration. Moreover, these novel materials were incorporated into devices for the purpose of studying the stability of perovskite solar cells, whilst ensuring the continued efficiency of the devices.
