Publication date: 11th March 2026
Perovskite solar cells (PSCs) have reached high power conversion efficiencies (PCE). Yet, record efficiencies rely on the evaporation of metals as electrode materials, which necessitates vacuum deposition. Additionally, non-noble metals can easily react with halides, resulting in long-term stability issues. Strong candidates to replace evaporated metal electrodes are carbon-based materials like graphite-based pastes deposited via printing and coatings of inks. Carbon electrodes promise cheap and fast fabrication, avoid unsuitable metals like gold, and may prove more stable than metal electrodes. Most PSCs with carbon electrodes are in the “regular” negative-intrinsic-positive (n-i-p) structure or the “hole-transport-layer-free” architecture. Here, we develop “inverted” p-i-n configuration carbon cells, motivated by the higher stability (as compared to n-i-p) usually observed in metal-contacted devices. However, we find incompatibilities of the common electron transport layers (ETLs) used in p-i-n devices like PCBM and BCP, with subsequent coating of the carbon electrodes. To address the processing and electron contact issues that we reveal, we introduce a double interlayer of atomic layer deposited tin-oxide (SnO2) and PEDOT:PSS (Poly(2,3-dihydrothieno-1,4-dioxin)-poly(styrenesulfonate)) between the ETL and the carbon electrode. We achieved a maximum power point tracked performance of 16.6% and maintained 94% of the initial performance aged outdoors for 500 h (T80 of about 1200 h). These results present a roadmap for printable and atmospheric processable perovskite PV technology, avoiding using rare metals.
