Publication date: 15th May 2026
Halide Perovskites have emerged as a revolutionary class of semiconductors, garnering intensive interest due to their exceptional and tunable optoelectronic properties, including high photoluminescence quantum yield (PLQY), high carrier mobility, and bandgap tunability across the visible spectrum. This versatility is demonstrated across various morphologies, nanocrystals (NCs), powders, thin films, and large single crystals, each offering unique advantages for specific applications. However, the dual challenges of lead toxicity and long-term instability have hindered their widespread adoption. While lead-free tin (Sn) halide perovskites are the most promising alternative, their poor stability, particularly the rapid oxidation of Sn2+ has severely limited the performance and lifetime of all device architectures.
In this presentation, we demonstrate a significant leap forward in stabilizing Sn-based perovskites. We detail how a synergistic approach combining targeted additive engineering and controlled light soaking passivates critical defects, enhancing the material's intrinsic stability. This strategy leads to a remarkable improvement in the operational lifetime of our solar cells, and we dissect the underlying mechanisms that go beyond simply preventing oxidation, enhancing stability and photoconversion performance.
This presentation provides a comprehensive investigation into the controlled synthesis and advanced applications of Sn-Perovskites. We show examples of the synthesis of powder as precursors for thin film formation and for application in LEDs, we will also investigate chiral perovskites. Single crystals have been synthesized by hydrothermal methodology with a without confined space. Overall, this study highlights the structural and compositional engineering required to exploit the full potential of halide perovskites, from nanoscopic to macroscopic forms, as a fundamental material system poised to drive breakthroughs in efficient illumination, coherent light generation, and sustainable chemical synthesis.
This presentation is partially funded by the Ministerio de Ciencia e Innovación of the Spanish Government by the project PLEDs, PID2022-140090OB-C21/AEI/10.13039/501100011033/FEDER and by project SUPERLASER that has received funding from the European Innovation Council (EIC) under grant agreement No. 101162503. The EIC receives support from the European Union’s Horizon Europe research and innovation programme. Funded by the European Union. The content provided in this presentation reflects the authors’ views only and do not necessarily reflect those of the European Union or the European Innovation Council and SMEs Executive Agency (EISMEA). Neither the European Union nor the granting authority can be held responsible for them.
