Hot carrier cooling and extraction dynamics of perovskite quantum dots
Qing Shen a, Yusheng Li a, Hua L a, Shota Yajima a, Chao Ding a
a The Univ. of Electro-Commun
Asia-Pacific International Conference on Perovskite, Organic Photovoltaics and Optoelectronics
Proceedings of Asia-Pacific International Conference on Perovskite, Organic Photovoltaics and Optoelectronics (IPEROP23)
Kobe, Japan, 2023 January 22nd - 24th
Organizers: Seigo Ito, Hideo Ohkita and Atsushi Wakamiya
Invited Speaker Session, Qing Shen, presentation 038
DOI: https://doi.org/10.29363/nanoge.iperop.2023.038
Publication date: 21st November 2022

Recently, photoexcited hot carriers (HCs) relaxation dynamics in halide perovskite materials have attracted much attention since the HCs cooling lifetimes was found to be unusually slow with orders of magnitude longer compared to those of the conventional semiconductor. On the other hand, the HCs cooling in perovskite quantum dots (PQDs) is size-dependent and the cooling time was observed to be around two orders of magnitude longer than that of their bulk counterparts [1], which suggests that the PQDs are promising candidates for hot-carrier solar cells (HCSCs). Therefore, a deeply understanding the hot carrier cooling and extraction dynamics in the PQDs has a profound implication for further developing the disruptive HCSCs. In this talk, we will introduce our recent research results on hot carrier cooling and extraction dynamics in PQDs, including both experimental results obtained using transient absorption (TA) spectroscopy and DFT theoretical calculation. We will discuss on how the A-site cations cross-exchange of the PQDs affects the hot carrier relaxation dynamics, and how about the hot carrier extraction from the PQDs to inorganic metal oxide substrates and fullerene [2-4].

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