Publication date: 4th October 2024
Metal halide perovskites used in perovskite solar cells (PSCs) achieve impressive power conversion efficiencies (PCEs) of up to 26.7%.1 Recent advances have improved PCEs in small-area PSCs and larger devices, including 1 cm² area and modules. These achievements are due to the unique properties of perovskite films, including micron-scale carrier diffusion lengths and strong optical absorption across the ultraviolet to near-infrared spectrum.
N,N-dimethylformamide (DMF) has been the primary solvent used for depositing perovskite thin films in combination with the antisolvent method. Although effective, this process has significant drawbacks: DMF's carcinogenicity, the environmental impact of using large quantities of antisolvents such as toluene and chlorobenzene, and the technical expertise required.
Our previous work established a technique for fabricating large-grain, highly crystalline perovskite thin films without employing the antisolvent method. This method utilized DMF as the primary solvent, complemented by a high-boiling-point, low vapor pressure auxiliary solvent, and a Lewis base.2~5
This study advances our prior findings by employing 2-methoxyethanol, a non-carcinogenic auxiliary solvent, alongside additives to achieve smooth, highly crystalline thin films without using the antisolvent method. The solar cell performance of devices with ITO or FTO / PFN /SnO₂ / perovskite / Spiro-OMeTAD / Ag configurations will be presented.5
This work was supported by the Grant-in-Aid for Scientific Research (C) from the Japan Society for the Promotion of Science (JSPS) [grant number 23K03921].