Materials and Processes for the Commercialization of Durable Perovskite Solar Cells
Takurou Murakami a
a National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Japan, 日本、〒305-0046 茨城県つくば市東1丁目1−1, つくば市, Japan
Invited Speaker, Takurou Murakami, presentation 041
Publication date: 5th November 2025

Perovskite solar cells (PSCs) have emerged as promising candidates for next-generation ultra-light photovoltaic technologies due to their bendable perovskite layers, enabling film-type solar cells.[1] Their fabrication through solution-based coating and printing of electron/hole transport layers and organic-metal-halide perovskites offers the potential for low-cost production. PSCs have achieved power conversion efficiencies exceeding 20% in small-area devices (~1 cm²), positioning them as high-efficiency, low-cost alternatives to conventional solar cells.

To realize the commercialization of PSCs, it is essential to overcome challenges related to long-term durability under environmental stressors such as heat, moisture, and light, as well as to establish scalable manufacturing processes. At AIST, we are developing robust materials and interface technologies to mitigate degradation, alongside advanced evaluation methodologies for optimizing layer thickness and band alignment. [2-10] One critical issue is the reduced thermal stability caused by dopants in hole transport materials (HTMs). To address this, we synthesized novel dopant-free organic HTMs, achieving over 1000 hours of operational stability at 85 °C. In parallel, we explored alternative dopants such as phenyl ethyl ammonium (PEA)-TFSI, which maintained high efficiency under thermal stress. To combat moisture-induced degradation, we introduced 1,4-phenyl bisphosphonic acid (PBPA) as an additive in the perovskite layer, significantly enhancing moisture resistance.

For acceleration of material screening and device optimization, we developed a fully automated PSC fabrication system capable of full-layer coating, back electrode deposition, and laser scribing. This presentation will provide a comprehensive overview of our research and development efforts at AIST, aimed at enabling the practical deployment of perovskite solar cell technologies.

We would like to thank NEDO for supporting R&D of perovskite solar cells as the Green Innovation Funding Projects for (JPNP21016).

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