Publication date: 5th November 2025
Vacuum thermal evaporation is attracting growing interest for perovskite solar cells due to its solvent-free processing and compatibility with large-area fabrication. Among vacuum-based approaches, sequential evaporation has recently achieved the highest efficiencies, yet precise control of the inorganic precursor layer remains a key challenge. Building on our previous additive-assisted co-evaporation studies, we apply this strategy to sequential vacuum evaporation by depositing PbI₂, CsI, and propylene urea (PU) prior to FAI deposition. The incorporation of PU significantly enhances the crystallinity and (00l) preferred orientation of the inorganic layer, which is transferred to the subsequently formed CsFAPbI₃ perovskite, resulting in improved overall crystallinity. Consequently, PU-assisted devices exhibit enhanced photovoltaic performance, with Jsc increasing from 20.31 to 23.37 mA cm⁻², Voc from 1.02 to 1.04 V, and PCE from 15.98% to 17.17%. These results demonstrate that additive-controlled inorganic-layer engineering is an effective route to improving device performance in vacuum-processed perovskite solar cells.Vacuum thermal evaporation is attracting growing interest for perovskite solar cells due to its solvent-free processing and compatibility with large-area fabrication. Among vacuum-based approaches, sequential evaporation has recently achieved the highest efficiencies, yet precise control of the inorganic precursor layer remains a key challenge. Building on our previous additive-assisted co-evaporation studies, we apply this strategy to sequential vacuum evaporation by depositing PbI₂, CsI, and propylene urea (PU) prior to FAI deposition. The incorporation of PU significantly enhances the crystallinity and (00l) preferred orientation of the inorganic layer, which is transferred to the subsequently formed CsFAPbI₃ perovskite, resulting in improved overall crystallinity. Consequently, PU-assisted devices exhibit enhanced photovoltaic performance, with Jsc increasing from 20.31 to 23.37 mA cm⁻², Voc from 1.02 to 1.04 V, and PCE from 15.98% to 17.17%. These results demonstrate that additive-controlled inorganic-layer engineering is an effective route to improving device performance in vacuum-processed perovskite solar cells.
