Unlocking the Potential of Aqueous and Aprotic Metal-Air Batteries
Nagore Ortiz-Vitoriano a b, Marina Enterría a, Domenico Frattini a, Estíbaliz García-Gaitán a c d, Arantzazu Letona a c, Lidia Medinilla a
a Centre for Cooperative Research on Alternative Energies (CIC energiGUNE), Basque Research and Technology Alliance (BRTA), Alava Technology Park, Albert Einstein 48, Vitoria-Gasteiz 01510, Spain
b Ikerbasque, Basque Foundation for Science, María Díaz de Haro 3, 48013 Bilbao, Spain.
c Departamento de Química Orgánica e Inorgánica, Universidad del País Vasco (UPV/EHU), P.O. Box 664, 48080 Bilbao, Spain
d CEGASA Energía SLU, Marie Curie, 1, Parque Tecnológico de Álava, 01510 Miñano, Spain
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS23 & Sustainable Technology Forum València (STECH23) (MATSUS23)
#GreenE - Advances in Green Energy Carriers
VALÈNCIA, Spain, 2023 March 6th - 10th
Organizers: Taeseup Song and Ungyu Paik
Invited Speaker, Nagore Ortiz-Vitoriano, presentation 296
DOI: https://doi.org/10.29363/nanoge.matsus.2023.296
Publication date: 22nd December 2022

Energy storage plays, undoubtedly, a fundamental role in the process of total decarbonization of the global economy that is expected to take place in the coming decades. The energy transition to a renewable and sustainable generation is the solution to reduce greenhouse gas emissions and thus achieve the European Commission´s goal of becoming the world´s first decarbonized economy. In this transition, beyond li-ion technologies will play a key role to meet the increasing energy demand that cannot be covered by Li-ion batteries solely. In this scenario, sodium-oxygen and zinc air batteries have become an attractive alternative due to their high gravimetric energy densities (1605 or 1108 Wh/kg based on Na2O2 or NaO2, respectively; and 1086 Wh/kg based on ZnO discharge products) resulting from the use of an oxygen-based phase-change reaction (potentially reducing the weight and freeing up space for other components).

In this talk, a general overview of these systems will be given along with the materials requirement and system performance. These batteries have been considered as the holy grail of battery research due to their high theoretical energy densities; however, several challenges remain to be solved before commercialization.

This work was funded by the R&D&I project PID2020-117626RA-I00, funded by MCIN/AEI/10.13039/501100011033. N. Ortiz-Vitoriano thanks the Ramon y Cajal grant (RYC-2020-030104-I) funded by MCIN/AEI/10.13039/501100011033 and by FSE invest in your future, respectively.

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