A Way to CO2-free power generation: Direct Ammonia fueled Solid Oxide Fuel Cells
Jong-Eun Hong a, Keejung Kim a, Jiyu Kim a, Heejin Kim a, Dong Woo Joh a, Seung-Bok Lee a, Hye-Sung Kim a, Tak-Hyoung Lim a, Seok-Joo Park a, Rak-Hyun Song a, Yongha Park a, Kee Young Koo a, Un-ho Jung a
a Korea Institute of Energy Research, 152, Gajeong-ro, Yuseong-gu, Daejeon, 305, Korea, Republic of
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS23 & Sustainable Technology Forum València (STECH23) (MATSUS23)
#GreenE - Advances in Green Energy Carriers
VALÈNCIA, Spain, 2023 March 6th - 10th
Organizers: Taeseup Song and Ungyu Paik
Invited Speaker, Jong-Eun Hong, presentation 298
DOI: https://doi.org/10.29363/nanoge.matsus.2023.298
Publication date: 22nd December 2022

Solid oxide fuel cells (SOFCs) are capable of providing high energy efficiency and fuel flexibility leading to use of hydrogen and hydrocarbons due to high operation temperature (600–800°C). Recently, ammonia (NH3) is considered as one of the most promising hydrogen carriers because of great advantages of zero-carbon emission, a high hydrogen content and worldwide infrastructures established for production, transport and storage. Thus, much effort has been given to directly utilize ammonia as a fuel for SOFCs, so called direct ammonia (DA)-SOFCs in which the fuel is decomposed hydrogen and nitrogen, and the released hydrogen is electrochemically oxidized in the anode consecutively. Thus, DA-SOFCs are believed to accomplish a CO2-free power generation with high efficiency. In this study, the current status on the development of SOFCs fed with ammonia, and strategical approaches to overcome technical issues limiting the development of DA-SOFCs will be introduced. In addition, results on the application of an exsolution catalyst to decompose the fuel in the anode of DA-SOFCs are present, which has proven the feasibility of ammonia fuel for high performance and reliable SOFCs.

This work was supported by Korea Institute of Energy Technology Evaluation and Planning for Renewable Energy Core Technology Development Project (20223030030090) and also conducted under the framework of the research and development program of the Korea Institute of Energy Research (C3-2467).

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