3D Printed Gas Diffusion Layer Electrode Consisting of Novel Oxide-Phosphide Heterostructure for Electrochemical CO2 Reduction
Niraj Nitish Patil a, Nadia Batool b, Damien Voiry b, Kevin M Ryan a, Tangi Aubert b, Shalini Singh a
a Department of Chemical Sciences and Bernal Institute, University of Limerick, Limerick, Ireland V94T9PX.
b University of Montpellier
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS Fall 2024 Conference (MATSUSFall24)
#NANOFUN - Functional Nanomaterials: from materials to applications.
Lausanne, Switzerland, 2024 November 12th - 15th
Organizers: Emmanuel Lhuillier and Shalini Singh
Poster, Niraj Nitish Patil, 367
Publication date: 28th August 2024

Metal-based species, such as oxides, are promising catalysts due to their structural and chemical stability during continuous catalysis processes. However, their catalytic activity is often limited, creating a significant opportunity for improvement. One effective strategy is the selective incorporation of another metal component to form a heterostructure, which can substantially enhance catalytic performance. In heterostructures, not only do the materials retain the inherent physicochemical benefits of their parent compounds, but unique properties emerging from synergetic effects at the heterointerfaces also contribute to improved electrocatalytic activity. In this project, colloidal chemistry was employed to develop a metal oxide-metal phosphide heterostructure. Detailed investigations into nucleation, growth kinetics, and surface chemistry provided mechanistic insights into heterostructure formation. Various characterization techniques further elucidated its structural and functional attributes. Additionally, the heterostructure, combined with silica cages, was used to fabricate gas diffusion electrodes through 3D printing. These electrodes demonstrated promising performance in the electrochemical reduction of CO2, yielding valuable products such as carbon monoxide (CO) and formate.

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