Publication date: 21st July 2025
The synthesis and characterization of thin-film plasmonic supercrystals of gold nanoparticles will be discussed.[1,2] The dense packing of the nanoparticles in the supercrystals leads to emergent optical properties due to extreme light-matter interactions.[3] The resulting enhanced near-fields in the structures can be exploited for surface-enhanced spectroscopies but also for plasmonic photocatalysis. [4,5] Towards such applications it is, in turn, also important to understand the thermal properties of the materials on relevant timescales.[6,7] The correlation of electron microscopy, spectroscopy and small-angle X-ray-scattering helps to understand how nanoparticle surface chemistry affects structure formation and how structure dictates the emerging properties. This is in particular interesting for anisotropic nanoparticles where the interplay of shape anisotropy and ligand properties leads to interesting new structures and near-field distributions which can be related to polarization-dependent optical properties.[8] With binary mixtures even more complex geometries can be obtained, providing plenty of room to explore for these polaritonic materials.