Probing the Effects of Doping on Mechanical and Electrical Properties in Organic Mixed Ionic-Electronic Conductors
Rajiv Giridharagopal a
a University of Washington, Seattle
Proceedings of MATSUS Fall 2025 Conference (MATSUSFall25)
D4 Organic Electrochemical Transistors – Materials and Device Properties - #OectMap
València, Spain, 2025 October 20th - 24th
Organizers: Scott Keene, Sabine Ludwigs and Tom van der Pol
Invited Speaker, Rajiv Giridharagopal, presentation 146
Publication date: 21st July 2025

Organic electrochemical transistors operate via electrochemical doping, where an applied gate potential in an electrolyte modulates the channel conductivity through counterion injection into and expulsion from the semiconducting polymer. This process, and the resulting current in devices, affects and is affected by the structure of the underlying organic mixed ionic-electronic conductor (OMIEC) and the polymer-electrolyte interface, ultimately impacting a range of properties including doping/dedoping kinetics, polymer mechanics, charge transport, and doping efficiency. Given the nanostructured nature of OMIECs, scanning probe microscopy techniques can reveal important information about the underlying process, particularly as these methods can be performed operando in aqueous electrolytes. Here we discuss microscopy-driven investigations using optical and atomic force microscopy methods to probe the OMIECs before, during, and after the electrochemical doping process. We use these methods to explore tradeoffs between sidechain chemistry and uptake, as well as how elastic modulus and adhesion change upon oxidation. Beyond mechanics, we discuss how materials can exhibit vastly different levels of doping efficiency, using a combination of Kelvin probe force microscopy and spectroelectrochemistry to provide insight into charge transport models and delocalized carrier density. Together, these methods link real-space operando measurements with device level performance and can provide a rational basis for optimizing materials.

© FUNDACIO DE LA COMUNITAT VALENCIANA SCITO
We use our own and third party cookies for analysing and measuring usage of our website to improve our services. If you continue browsing, we consider accepting its use. You can check our Cookies Policy in which you will also find how to configure your web browser for the use of cookies. More info