Publication date: 21st July 2025
Understanding charge carrier dynamics and transport in halide perovskite semiconductors is essential for optimising their performance in optoelectronic applications, such as photovoltaics, light-emitting diodes, and photodetectors. Here, we employ transient photoluminescence microscopy and optical spectroscopy to directly visualize spatiotemporal carrier dynamics with high spatial and temporal resolution. We first study mixed lead-tin perovskites to elucidate the impact of compositional disorder on carrier transport. [1-5] We observe that increasing the tin-to-lead ratio raises the background hole concentration, while the most alloyed compositions exhibit the lowest diffusion coefficients, likely a consequence of alloy-induced disorder. Separately, we investigate quantum well structures to explore the effects of the quantum and dielectric confinement in thin films. [6-7] We find that confinement leads to a blue shift in optical transitions, enhanced excitonic character, and accelerated charge carrier recombination. Collectively, our results demonstrate how the spatiotemporal dynamics of charge carriers are affected by microscopic material disorder and macroscopic confinement effects, offering insights for the design of high-performance halide perovskite devices.
Agency for Science, Technology and Research (A*STAR, Singapore)