Charge Carrier Dynamics and Transport in Halide Perovskite Semiconductors
Xian Wei Chua a b, Youcheng Zhang a b, Luke R.W. White c d e, Stefano Pecorario b, Robert J.E. Westbrook a, Henning Sirringhaus b, Annalisa Bruno c e f, Akshay Rao b, Samuel D. Stranks a b
a Department of Chemical Engineering and Biotechnology, University of Cambridge, Philippa Fawcett Drive, Cambridge CB3 0AS, United Kingdom
b Cavendish Laboratory, Department of Physics, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE, United Kingdom
c Energy Research Institute @ NTU, Nanyang Technological University, Research Techno Plaza, 50 Nanyang Drive, Singapore 637553
d Interdisciplinary Graduate Programme, Nanyang Technological University, Singapore 637553
e School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798
f School of Physical and Mathematical Science, Nanyang Technological University, 21 Nanyang Link, Singapore 637371
Proceedings of MATSUS Fall 2025 Conference (MATSUSFall25)
E8 Materials in motion: Imaging nanoscale dynamics with photons and electrons - #NanoDyn
València, Spain, 2025 October 20th - 24th
Organizers: Wyatt Curtis and Seryio Saris
Oral, Xian Wei Chua, presentation 151
Publication date: 21st July 2025

Understanding charge carrier dynamics and transport in halide perovskite semiconductors is essential for optimising their performance in optoelectronic applications, such as photovoltaics, light-emitting diodes, and photodetectors. Here, we employ transient photoluminescence microscopy and optical spectroscopy to directly visualize spatiotemporal carrier dynamics with high spatial and temporal resolution. We first study mixed lead-tin perovskites to elucidate the impact of compositional disorder on carrier transport. [1-5] We observe that increasing the tin-to-lead ratio raises the background hole concentration, while the most alloyed compositions exhibit the lowest diffusion coefficients, likely a consequence of alloy-induced disorder. Separately, we investigate quantum well structures to explore the effects of the quantum and dielectric confinement in thin films. [6-7] We find that confinement leads to a blue shift in optical transitions, enhanced excitonic character, and accelerated charge carrier recombination. Collectively, our results demonstrate how the spatiotemporal dynamics of charge carriers are affected by microscopic material disorder and macroscopic confinement effects, offering insights for the design of high-performance halide perovskite devices.

Agency for Science, Technology and Research (A*STAR, Singapore)

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