Microscopic insights into the performance and stability challenges of perovskite solar cells
Sofiia Kosar a
a Center for Renewable Energy and Storage Technologies (CREST), Physical Sciences and Engineering Division, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900, Saudi Arabia
Proceedings of MATSUS Fall 2025 Conference (MATSUSFall25)
A.7 Simulation and Characterization of OptoElectroIonic Devices: Performance, Degradation Mechanisms and Stability - #SimChar
València, Spain, 2025 October 20th - 24th
Organizers: Pilar López Varo and Sonia R. Raga
Invited Speaker, Sofiia Kosar, presentation 219
Publication date: 17th July 2025

Ensuring high performance and long-term stability of perovskite solar cells (PSCs) is essential for their transition to large-scale industrial deployment. However, device-level quality of PSCs is often limited by microscopic inhomogeneities within the active perovskite layer - such as local variations in composition,  structure, and optoelectronic response - which can adversely affect both device performance and stability.

Identifying and understanding these local defects is critical for improving device reliability. Given the complex composition and polycrystalline nature of perovskite materials, imaging techniques with high spatial resolutions are essential for identifying and characterizing such local variations [1,2].

In this talk, I will discuss how advanced imaging and spectroscopic techniques - ranging from ultraviolet photoemission to infrared scanning probe microscopies - can shed light on the microscopic origins of performance losses and degradation in PSCs. These insights provide a deeper understanding of the detrimental roles of microscopic inhomogeneities in shaping macroscopic device behavior of PSCs, informing strategies to improve their performance and stability.

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