Publication date: 17th July 2025
Electrochemical technologies such as batteries, catalysts and fuel cells will play a critical role in the world’s green-energy transition. At the crux of these (and other) electrochemical energy devices lie a combination of electron and ion (charge) transfer processes, impacting everything from durability to efficiency. On mesoscopic timescales (ns to s) we have a fantastic understanding of ionic-electronic transport related phenomena in electrochemical systems. However, when it comes to faster femtosecond/picosecond timescales our insight remains limited. This is a critical gap. Because in this time range lie many of the electron and ion mediated (redox) reactions, liquid phase rearrangements (solvation) and lattice dynamics that ultimately set the performance of the electrochemical materials that we need to push for reaching net-zero.
Using Li-ion batteries as an example, I will discuss how my team and I are seeking to capture and control ultrafast dynamics in electrochemical systems. I will specifically focus on our development of light-shaping (computational imaging) methods and IR/X-ray free-electron laser (FEL) spectroscopies to probe processes such as picosecond ion hops and femtosecond electron-lattice (polaron) interactions in batteries. I will delve into the impact of our results for the refinement of charge transport theories and battery materials discovery, as well as more generally highlighting the power of FELs for tracking processes that have thus-far been beyond spectroscopic probing, such as stochastic charge and structural motion. I will finish by sharing my vision to follow and tame ultrafast, performance defining, steps in other clean-energy systems, especially where the primary excitations are not necessarily driven by light e.g., electrocatalysts. And new quantum imaging/spectroscopy techniques my team and I are working on for characterising energy materials at ultralow photon fluxes, critical for avoiding material damage, and revealing otherwise inaccessible material properties.